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TOPIC 2: BASIC EMISSION PROCESSES  
 


The energy content (i.e., calorific value or heating value) of fuels is also an inherent chemical property. However, calorific values vary more widely between and within fuel types, as they are dependent upon the composition of chemical bonds in the fuel. Given these variations and the relationship between carbon content and calorific values, carbon content values for estimating CO2 emissions from fossil fuel combustion are expressed in terms of carbon per energy unit. This form generally provides more accurate emission estimates than if carbon content factors were expressed in terms of mass or volume.

Net Calorific Values (NCVs) measure the quantity of heat liberated by the complete combustion of a unit volume or mass of a fuel, assuming that the water resulting from combustion remains as a vapor, and the heat of the vapor is not recovered. Gross calorific values (GCVs), in contrast, are estimated assuming that this water vapor is completely condensed and the heat is recovered, and are therefore slightly larger. Default data in the Revised 1996 IPCC Guidelines are based on NCVs.

Country-specific net calorific values Appendix 2.1A.3, Table 2.4 of Revised 1996 IPCC Guidelines

Figure 7. Fossil Fuel Combustion